Never rendered a round corner but done plenty of internal stuff, walls and ceilings. If its walls i usually go left to right and cross hatch it, watch out for hollows and fill in as you go. The trick is to keep you're trowel at such an angle that you don't dig the blade in on opposite side from contact side. Saying that it is quite tricky and requires a lot of practice! Good luck.
On that note was wondering about this the other day, saw a rendered wall that had been floated to a smooth finish, it was curved and was wondering how it was done! Do you just guage off and float as normal or is there more to it?